Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Measurements of the thermal conductivity of ethene in the supercritical region

Neindre, B. L., Lombardi, G., Desmarest, P.[Ph.], Kayser, M., Zaripov, Z. I., Gumerov, F., Garrabos, Y.
Fluid Phase Equilib. 2018, 459, 119-128
ABSTRACT
Measurements of the thermal conductivity of ethene performed for the first time, in a coaxial cylinder cell, operating in steady state conditions are reported. The measurements of the thermal conductivity of ethene were carried out along eight quasi-isotherms above the critical temperature. The present data cover the temperature range from 283.46 K to 425.00 K, and the pressure range 0.1 to 100 MPa. An analysis of the different sources of error leads to an estimated uncertainty (0.95 level of confidence) of +-3%. The parameters of a background equation were determined from experimental data in order to analyze the critical enhancement of the thermal conductivity as a function of temperature and density. Based on the measurement of more than 500 experimental points, a phenomenological equation is provided to describe the thermal conductivity of ethene, from 270 K to 425 K and densities up to 500 kg m-3.
Compounds
# Formula Name
1 C2H4 ethene
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Thermal conductivity, W/m/K ; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Gas
  • Coaxial cylinder method
  • 7
  • POMD
  • 1
  • Thermal conductivity, W/m/K ; Fluid (supercritical or subcritical phases)
  • Temperature, K; Fluid (supercritical or subcritical phases)
  • Pressure, kPa; Fluid (supercritical or subcritical phases)
  • Fluid (supercritical or subcritical phases)
  • Coaxial cylinder method
  • 256