Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

New experimental density data and derived thermophysical properties of carbon dioxide - Sulphur dioxide binary mixture (CO2 - SO2) in gas, liquid and supercritical phases from 273 K to 353 K and at pressures up to 42 MPa

Nazeri, M.[Mahmoud], Chapoy, A.[Antonin], Valtz, A.[Alain], Coquelet, C.[Christophe], Tohidi, B.[Bahman]
Fluid Phase Equilib. 2017, 454, 64-77
ABSTRACT
Due in part to the toxicity of the CO2-SO2 binary system, there are no density data available in the literature. Densities for this system were measured using a vibrating tube densitometer (VTD), Anton Paar DMA 512, and the forced path mechanical calibration (FPMC) method in the gas, liquid and supercritical phases at pressures up to 41.7 MPa. The mole fraction of the mixture was 0.9478 CO2 + 0.0522 SO2 at 298 K and 0.9503 CO2 + 0.0497 SO2 at 273, 283, 323 and 353 K. The compressibility factor, isobaric heat capacity and bubble points were also derived from the measured densities. The classical cubic equations of state, i.e., Soave-Redlich-Kwong (SRK), Peng-Robinson (PR) and Valderrama version of Patel-Teja (VPT) with the CO2 volume correction term and Peneloux shift parameter in addition to a multi parameter EoS based on Helmholtz energy were evaluated using the measured density data. The most accurate EoSs for the investigated system were the multi parameter EoS and the PR-CO2 with overall AAD of 0.6 % and 1.0 %, respectively.
Compounds
# Formula Name
1 O2S sulfur dioxide
2 CO2 carbon dioxide
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Mole fraction - 2; Gas
  • Gas
  • Vibrating tube method
  • 63
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • Vibrating tube method
  • 153
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Mole fraction - 2; Gas
  • Gas
  • Vibrating tube method
  • 23
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • Vibrating tube method
  • 68
  • POMD
  • 1
  • 2
  • Mass density, kg/m3 ; Fluid (supercritical or subcritical phases)
  • Temperature, K; Fluid (supercritical or subcritical phases)
  • Pressure, kPa; Fluid (supercritical or subcritical phases)
  • Mole fraction - 2; Fluid (supercritical or subcritical phases)
  • Fluid (supercritical or subcritical phases)
  • Vibrating tube method
  • 136