Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Monoethanolamine-based deep eutectic solvents, their synthesis and characterization

Mjalli, Farouq S., Murshid, Ghulam, Al-Zakwani, Suad, Hayyan, Adeeb
Fluid Phase Equilib. 2017, 448, 30-40
ABSTRACT
Since reporting the Reline (choline chloride and urea at 1:2 molar ratio) deep eutectic solvent (DES) few years ago, a diversity of similar solvents have been prepared, characterized and used in different practical applications. The need is still available for converting some conventional solvents into a eutectic formulation for different reasons. In this work, the monoethanolamine (MEA) is combined with three different quaternary salts to form DES at different molar compositions. The resulting DESs were characterized by measuring their main physical properties including melting point, density, viscosity, conductivity, and refractive index within the temperature range of 298.15 358.15 K. These new eutectic fluids have melting points below 279.15 K and of relatively low density and viscosity values. The molar composition of these DESs have significant effect on their physical properties. These new fluids can be utilized for a variety of applications involving adsorptive gas separation and particularly carbon dioxide capture.
Compounds
# Formula Name
1 C5H14ClNO choline chloride
2 C19H18BrP methyltriphenylphosphonium bromide
3 C16H36BrN tetrabutylammonium bromide
4 C2H7NO 2-aminoethan-1-ol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 4
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Amount ratio of solute to solvent - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • DTA
  • 4
  • POMD
  • 1
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 28
  • POMD
  • 1
  • 4
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 28
  • POMD
  • 1
  • 4
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 28
  • POMD
  • 1
  • 4
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Ring tensiometer
  • 28
  • POMD
  • 4
  • 3
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Amount ratio of solute to solvent - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • DTA
  • 4
  • POMD
  • 4
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 28
  • POMD
  • 4
  • 3
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 28
  • POMD
  • 4
  • 3
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 28
  • POMD
  • 4
  • 3
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 3; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Ring tensiometer
  • 28
  • POMD
  • 4
  • 2
  • Solid-liquid equilibrium temperature, K ; Liquid
  • Amount ratio of solute to solvent - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • DTA
  • 3
  • POMD
  • 4
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 28
  • POMD
  • 4
  • 2
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Capillary tube (Ostwald; Ubbelohde) method
  • 28
  • POMD
  • 4
  • 2
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 28
  • POMD
  • 4
  • 2
  • Surface tension liquid-gas, N/m ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 2; Liquid
  • Liquid
  • Air at 1 atmosphere
  • Ring tensiometer
  • 28