ABSTRACT

A systematic isobaric vapor-liquid equilibrium (VLE) study of seven binary mixtures of 1- butyl-3-methylimidazolium chloride, [C4C1im][Cl], and methanol, propan-1-ol, propan-2-ol, butan- 1-ol, butan-2-ol, tert-butanol (2-methylpropan-2-ol), iso-butanol (2-methylpropan-1-ol) and pentan- 1-ol, was carried out at three different system pressures (0.1, 0.07 and 0.05) MPa. Activity coefficients were estimated from the boiling temperatures of the binary mixtures. soft-SAFT equation of state was used to describe the experimental VLE data and all together, allowed to infer and understand the effect of the alcohol alkyl chain length and structural isomerism on the molecular interactions between the IL and the alcohols.

Compounds

#	Formula	Name
1	CH4O	methanol
2	C3H8O	propan-1-ol
3	C3H8O	propan-2-ol
4	C4H10O	butan-1-ol
5	C4H10O	butan-2-ol
6	C4H10O	2-methyl-1-propanol
7	C4H10O	2-methylpropan-2-ol
8	C5H12O	pentan-1-ol
9	C8H15ClN2	1-butyl-3-methylimidazolium chloride

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Phase	Method	#Points
POMD	1 9	Boiling temperature at pressure P, K ; Liquid	Pressure, kPa; Liquid Mole fraction - 1; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	69
POMD	2 9	Boiling temperature at pressure P, K ; Liquid	Pressure, kPa; Liquid Mole fraction - 2; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	66
POMD	3 9	Boiling temperature at pressure P, K ; Liquid	Pressure, kPa; Liquid Mole fraction - 3; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	102
POMD	4 9	Boiling temperature at pressure P, K ; Liquid	Pressure, kPa; Liquid Mole fraction - 4; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	58
POMD	5 9	Boiling temperature at pressure P, K ; Liquid	Pressure, kPa; Liquid Mole fraction - 5; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	103
POMD	7 9	Boiling temperature at pressure P, K ; Liquid	Pressure, kPa; Liquid Mole fraction - 7; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	65
POMD	6 9	Boiling temperature at pressure P, K ; Liquid	Pressure, kPa; Liquid Mole fraction - 6; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	60
POMD	8 9	Boiling temperature at pressure P, K ; Liquid	Pressure, kPa; Liquid Mole fraction - 8; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	64

Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Evaluation of the solvent structural effect upon the vapor-liquid equilibrium of [C4C1im][Cl] + Alcohols

Chouireb, N.[Naima], Khan, I.[Imran], Crespo, E. A.[Emanuel A.], Oliveira, M. B.[Mariana B.], Llovell, F.[Felix], Vega, L. F.[Lourdes F.], Tafat-Igoudjilene, O., Kaci, A. A., Santos, L. M. N. B. F.[Luis M. N. B. F.], Carvalho, P. J.[Pedro J.], Coutinho, J. A. P. [Joao A. P.]

ABSTRACT