Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Isobaric heat capacities of exo-tetrahydrodicyclopentadiene at temperatures from 323 K to 523 K and pressures up to 6 MPa

Zhang, Q.[Qian], Liu, X.[Xiangyang], He, M.[Maogang]
Fluid Phase Equilib. 2017, 434, 102-106
ABSTRACT
The isobaric molar heat capacities of exo-tetrahydrodicyclopentadiene (exo-THDCPD) in the temperature range of 323 K - 523 K and at pressures up to 6 MPa were measured by using a flow calorimeter. The results show that the isobaric heat capacities of exo-THDCPD increase gradually with increasing temperature at fixed pressure and decrease with increasing pressure at fixed temperature. The experimental heat capacities of exo-THDCPD are compared with the reported heat capacity data and calculated values of exo-THDCPD using the Helmholtz's free energy equation, and are also compared with the reported heat capacity data of decane. On the basis of the experimental data, a correlation equation was proposed to calculate the isobaric heat capacity of exo-THDCPD. The calculated values agree well with the experimental data.
Compounds
# Formula Name
1 C10H16 exo-tetrahydrodicyclopentadiene
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Molar heat capacity at constant pressure, J/K/mol ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Flow calorimetry
  • 91