Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

ABSTRACT

This study aims to investigate the temperature dependence of the physicochemical properties of five cations paired with bis(trifluoromethylsulfonyl)imide anion, namely 1-(2-methoxyethyl)-1- methylpiperidinium bis(trifluoromethylsulfonyl)imide, 1-(2-methoxyethyl)-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide, N-methoxyethyl-N-methylmorpholinium bis(trifluoromethylsulfonyl) imide, N-ethyl-N,N-dimethyl-2-methoxyethylammonium bis(trifluoromethylsulfonyl)imide and ethyldimethyl- propylammonium bis(trifluoromethylsulfonyl)imide. The density, viscosity, conductivity and surface tension of the resulting ionic liquids (ILs) have been determined within the temperature range (298.15e353.15) K. It has been found that all ILs exhibited Arrhenius behavior for conductivity and viscosity while the surface tension and density followed a linear trend. A satisfactory agreement was obtained between our experimental densities and those predicted by the group contribution model. This study is essential in the application of these ILs for process design and will reinforce the development of new correlations and other predictive methods in particular when the physicochemical properties are scarce, like in the case of morpholinium-based ILs.