Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

ABSTRACT

Liquid-liquid equilibrium (LLE) temperatures have been determined for the mixtures: phenyl acetone + CH3(CH2)uCH3 (u = 8,10,12,14), or + 2,2,4-trimethylpentane, benzyl acetone + decane and benzyl acetate + dodecane by means of the critical opalescence method using a laser scattering technique. All the systems are characterized by an upper critical solution temperature (UCST). The coexistence curves have a rather flat maximum, and become shifted to higher concentrations of phenyl acetone when the alkane size increases. Aromatic alkanone, or alkanal or alkanoate + alkane, or + benzene mixtures have been investigated using DISQUAC. The interaction parameters for the X/aliphatic and X/ aromatic contacts (X = CO, CHO, COO) are reported. The model correctly describes experimental data on LLE, vapour-liquid equilibria (VLE) and excess molar enthalpies. UNIFAC (Dortmund version) results are poorer. This shows that new UNIFAC groups for the mentioned aromatic systems should be defined. Proximity effects depend on the number of CH2 groups (n) between the phenyl ring and the polar group of the aromatic compound considered. Proximity effects lead to enhanced dipolar interactions, which change in the order n = 1 greater than n = 2 greater than n = 0. Comparison of thermodynamic properties for systems with isomeric molecules (benzyl ethanoate and phenyl acetone) shows that dispersive interactions are more relevant in the benzyl ethanoate system.