Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Gaseous prhoTx properties for binary mixtures of HFO1234ze(E) + HC290

Zhang, H.[Haiyang], Gong, M.[Maoqiong], Li, H.[Huiya], Guo, H.[Hao], Dong, X.[Xueqiang], Wu, J.[Jianfeng]
Fluid Phase Equilib. 2016, 408, 232-239
ABSTRACT
The prTx properties for binary mixtures of trans-1,3,3,3-tetrafluoropropene (HFO1234ze(E)) + propane (HC290) were performed in the gaseous phase by a compact single-sinker densimeter. The experimental measurements covered temperatures from (258.146 to 293.353) K, pressures from (0.0989 to 0.8255) MPa, and compositions from (0.1680 to 0.8949) mole fractions of HFO1234ze(E). The standard uncertainties in this work were estimated to be within 5 mK for temperature, 200 Pa for pressure, 0.0003 for compositions and 0.06% for density. A truncated virial equation of state was employed to correlate the present experimental prTx data. Good agreement with the virial equation for the experimental pressures and densities were found with average absolute relative deviations of 0.051% and 0.055%, respectively. In addition, the truncated virial equation with six different combinations of empirical correlating methods for the second and the third virial coefficients were used to predict the experimental densities of HFO1234ze(E), HC290 and their mixtures, where good agreement were also found.
Compounds
# Formula Name
1 C3H2F4 trans-1,3,3,3-tetrafluoropropene
2 C3H8 propane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Mass density, kg/m3 ; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Gas
  • single sinker densimeter
  • 26
  • POMD
  • 2
  • Mass density, kg/m3 ; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Gas
  • single sinker densimeter
  • 30
  • POMD
  • 2
  • 1
  • Mass density, kg/m3 ; Gas
  • Temperature, K; Gas
  • Pressure, kPa; Gas
  • Mole fraction - 1; Gas
  • Gas
  • single sinker densimeter
  • 137