Name: ThermoML Representation of Published Experimental Data from Fluid Phase Equilibria (0378-3812, Elsevier)
Creator: Thermodynamics Research Center
License: https://www.nist.gov/open/license

ABSTRACT

Vapor-liquid equilibrium data for ethyl trifluoroacetate + trifluoroacetic acid, ethyl trifluoroacetate + ethanol, and trifluoroacetic acid + water at the pressure 101.3 kPa were measured with a modified Rose still. The thermodynamic consistency of the VLE data was confirmed by Herrington's method. The VLE data were correlated by the NRTL and Wilson models with satisfactory results, and the interaction parameters of these mixtures were estimated.

Compounds

#	Formula	Name
1	C4H5F3O2	ethyl trifluoroacetate
2	C2H6O	ethanol
3	C2HF3O2	trifluoroethanoic acid
4	H2O	water

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Boiling temperature at pressure P, K ; Liquid	Pressure, kPa; Liquid		Liquid Gas	Closed cell (Static) method	1
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	2	Boiling temperature at pressure P, K ; Liquid	Pressure, kPa; Liquid		Liquid Gas	Closed cell (Static) method	1
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	3	Boiling temperature at pressure P, K ; Liquid	Pressure, kPa; Liquid		Liquid Gas	Closed cell (Static) method	1
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	3	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	4	Boiling temperature at pressure P, K ; Liquid	Pressure, kPa; Liquid		Liquid Gas	Closed cell (Static) method	1
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	4	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	3 4	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 3; Liquid	Pressure, kPa; Gas	Liquid Gas	Ebulliometric method (Recirculating still)	31
POMD	3 4	Mole fraction - 3 ; Gas	Mole fraction - 3; Liquid	Pressure, kPa; Gas	Gas Liquid	Chromatography	31
POMD	2 1	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Gas	Liquid Gas	Ebulliometric method (Recirculating still)	32
POMD	2 1	Mole fraction - 1 ; Gas	Mole fraction - 1; Liquid	Pressure, kPa; Gas	Gas Liquid	Chromatography	32
POMD	3 1	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Gas	Liquid Gas	Ebulliometric method (Recirculating still)	38
POMD	3 1	Mole fraction - 1 ; Gas	Mole fraction - 1; Liquid	Pressure, kPa; Gas	Gas Liquid	Chromatography	36

Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Isobaric vapor-liquid equilibrium of trifluoroacetic acid + water, trifluoroacetic acid + ethyl trifluoroacetate and ethyl trifluoroacetate + ethanol binary mixtures

Huang, Z.[Zhixian], Li, L.[Ling], Zhou, M.[Miaomiao], Jiang, H.[Haiming], Qiu, T.[Ting]

ABSTRACT