Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Solubility of ethylene in methyl propionate

Shariati, A.[Alireza], Florusse, L. J.[Louw J.], Peters, C. J.[Cor J.]
Fluid Phase Equilib. 2015, 387, 143-145
ABSTRACT
In this work, the solubility of ethylene in methyl propionate was measured within a temperature range of 283.5 - 464.8 K and pressures up to 10.7 MPa. Experiments were carried out using the Cailletet apparatus, which uses a synthetic method for the experiments. The critical points of several isopleths have also been determined experimentally for this system. The Peng-Robinson equation of state was used to predict the solubility of ethylene in methyl propionate. The absolute average deviation for all of the calculated points was 5.8%.
Compounds
# Formula Name
1 C2H4 ethene
2 C4H8O2 methyl propanoate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Closed cell (Static) method
  • 88
  • POMD
  • 1
  • 2
  • Critical temperature, K ; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Gas
  • Visual observation in an unstirred cell
  • 4
  • POMD
  • 1
  • 2
  • Critical pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Gas
  • Direct measurement
  • 4