Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Isobaric vapor liquid equilibrium for binary system of methyl myristate + methyl palmitate at 0.5, 1.0 and 1.4 kPa

Chen, R.[Ruru], Ding, H.[Hui], Liu, M.[Mingchao], Qi, J.[Jinlong], Zhou, H.[Hang], Chen, N.[Ning]
Fluid Phase Equilib. 2014, 382, 133-138
ABSTRACT
Isobaric vapor liquid equilibrium (VLE) data for the binary system of methyl myristate + methyl palmitate at 0.5, 1.0 and 1.4 kPa were measured by a VLE modified Othmer still. The esters used in this paper are the major components of biodiesel. The experimental data in the vaccum conditions passed the Wisniak consistency test and point consistency test of Van Ness test, which ensure the reliability of experimental data. Furthermore, these VLE data were correlated with Nonrandom two-liquid (NRTL) activity coefficient model and Wilson model, and predicted by UNIFAC and Dortmund (modified UNIFAC) models. The results indicate that the calculated values of these four models agree well with the experimental data.
Compounds
# Formula Name
1 C15H30O2 methyl tetradecanoate
2 C17H34O2 methyl hexadecanoate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Ebulliometric method (Recirculating still)
  • 38
  • POMD
  • 2
  • 1
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 38