Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Osmotic and activity coefficients of alpha, omega-amino acids in aqueous solutions at 298.15 K

Cadena, J. C., Romero, C. M.
Fluid Phase Equilib. 2014, 370, 8-11
ABSTRACT
The osmotic coefficients of aqueous solutions of the alpha, omega-amino acids: 3-aminopropanoic acid, 4-aminobutanoic acid, 5-aminopentanoic acid and 6-aminohexanoic acid were measured using the isopiestic method at 298.15 K. The activity coefficients of these solutes were calculated from the experimental osmotic coefficients and the pairwise free energy coefficients for solute-solute interactions were obtained using the McMillan-Mayer theory. The results are compared with the activity coefficients of alpha-amino acids and are discussed in terms of solute-solute interactions.
Compounds
# Formula Name
1 C3H7NO2 3-aminopropanoic acid
2 C4H9NO2 4-aminobutanoic acid
3 C5H11NO2 5-aminovaleric acid
4 C6H13NO2 6-aminohexanoic acid
5 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 5
  • Osmotic coefficient ; Liquid
  • Molality, mol/kg - 1; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • ISOPIE
  • 8
  • POMD
  • 2
  • 5
  • Osmotic coefficient ; Liquid
  • Molality, mol/kg - 2; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • ISOPIE
  • 8
  • POMD
  • 3
  • 5
  • Osmotic coefficient ; Liquid
  • Molality, mol/kg - 3; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • ISOPIE
  • 8
  • POMD
  • 4
  • 5
  • Osmotic coefficient ; Liquid
  • Molality, mol/kg - 4; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Liquid
  • ISOPIE
  • 8