Thermodynamic stability boundaries of carbon dioxide + cyclopentane, carbon dioxide + cyclopentanone,and carbon dioxide + fluorocyclopentane mixed hydrates have been investigated in the range of 274.19 to 293.72 K and up to 4.88 MPa. The phase equilibrium curves of the structure-II mixed hydrates are located at a temperature remarkably higher than that of the structure-I simple carbon dioxide hydrate.The highest temperature point of each four-phase (hydrate, aqueous, cyclopentane derivative-rich, and gas phases) equilibrium curve was 292.60 K (for the first system), 284.78 K (for the second system), and 293.72 K (for the third system).
Compounds
#
Formula
Name
1
C5H10
cyclopentane
2
C5H8O
cyclopentanone
3
C5H9F
fluorocyclopentane
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.