This work presents measurements of the solubility of adipic acid in water, acetic acid, acetic acid-water mixture (ratio of 1:1 v/v), cyclohexanol and cyclohexanone at the temperature ranging from 303.0 to 403.0 K. The reliability experimental method used in this work for studying the solubility of adipic acid was verified using the published solubility data at low temperatures. The modified Apelblat equation was applied in order to correlate the solubility of adipic acid in the above-mentioned solvents. The results showed that data obtained from our method were acceptable for measuring the solubility of adipic acid at high temperatures. The solubilities of adipic acid obtained from the modified Apelblat equation fitted well with the experimental data. The total average relative deviation was 2.55%. Moreover, the molar enthalpy and the molar entropy of dissolution of adipic acid in water, acetic acid, acetic acid-water mixtures, cyclohexanol and cyclohexanone at temperatures ranging from 303.0 to 403.0 K were calculated.
Compounds
#
Formula
Name
1
C6H10O4
1,6-hexanedioic acid
2
C2H4O2
acetic acid
3
C6H12O
cyclohexanol
4
C6H10O
cyclohexanone
5
H2O
water
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.