ABSTRACT

The vapor pressure of the pure component of methyl phenyl carbonate (MPC) was measured at temperatures ranging from 378 K to 488 K. The experimental vapor pressures could be fit well with a three-parameter Antoine equation. Isobaric vapor-liquid equilibria for binary systems (MPC + methanol and MPC + dimethyl carbonate) were determined using a dynamic method at 101.3 kPa. They were correlated with Wilson, NRTL and UNIQUAC models. In addition, excess molar volumes and deviations in molar refractivity at 298.15 K were recorded for the same binary systems using a digital vibrating tube densitometer and a precision digital refractometer. The excess molar volume and deviation in molar refractivity data were in good agreement with the predictions of the Redlich-Kister equation.

Compounds

#	Formula	Name
1	CH4O	methanol
2	C3H6O3	dimethyl carbonate
3	C8H8O3	methyl phenyl carbonate

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	1	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	Ebulliometric method (Recirculating still)	1
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	2	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	Ebulliometric method (Recirculating still)	1
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	3	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	3	Boiling temperature at pressure P, K ; Liquid	Pressure, kPa; Liquid		Liquid Gas	Ebulliometric method (Recirculating still)	23
POMD	2 3	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	22
POMD	2 3	Mole fraction - 3 ; Gas	Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Gas Liquid	Chromatography	22
POMD	2 3	Mass density, kg/m3 ; Liquid	Mole fraction - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	11
POMD	2 3	Refractive index (Na D-line) ; Liquid	Mole fraction - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	11
POMD	1 3	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid Gas	Ebulliometric method (Recirculating still)	22
POMD	1 3	Mole fraction - 3 ; Gas	Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Gas Liquid	Chromatography	22
POMD	1 3	Mass density, kg/m3 ; Liquid	Mole fraction - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	11
POMD	1 3	Refractive index (Na D-line) ; Liquid	Mole fraction - 3; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	11

Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Isobaric vapor-liquid equilibrium at 101.3 kPa and excess properties at 298.15 K for binary mixtures of methyl phenyl carbonate with methanol or dimethyl carbonate

Hwang, I.-C.[In-Chan], Shin, S.-H.[Sang-Hong], Jeong, I.-Y.[In-Yong], Jeon, Y.-H.[Yeong-Hwan], Park, S.-J.[So-Jin]

ABSTRACT