ABSTRACT

The object of this study is to measure the liquid-liquid equilibrium (LLE) data in fluorous solvent (perfluorohexane and Galden(R) HT-135) mixtures, which are used as environmentally benign reaction solvents.The LLE data of perfluorohexane + n-alkane (C7, C9, and C10) mixtures were measured to determine thephase behavior of perfluorohexane + n-alkane (C6 to C10) mixtures. The LLE for Galden HT-135(R)+ dibutylether/butyl acetate mixtures were measured up to the upper critical solution temperature (UCST). The experimental results for the LLE were represented using the NRTL activity coefficient model.

Compounds

#	Formula	Name
1	C7H16	heptane
2	C6F14	perfluorohexane
3	C9H20	nonane
4	C10H22	decane

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1 2	Mole fraction - 2 ; Liquid mixture 1	Temperature, K; Liquid mixture 1	Pressure, kPa; Liquid mixture 1	Liquid mixture 1 Liquid mixture 2	Phase equilibration	21
POMD	3 2	Mole fraction - 2 ; Liquid mixture 1	Temperature, K; Liquid mixture 1	Pressure, kPa; Liquid mixture 1	Liquid mixture 1 Liquid mixture 2	Phase equilibration	22
POMD	4 2	Mole fraction - 2 ; Liquid mixture 1	Temperature, K; Liquid mixture 1	Pressure, kPa; Liquid mixture 1	Liquid mixture 1 Liquid mixture 2	Phase equilibration	19

Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Liquid-liquid equilibria containing fluorous solvents as environmentally benign solvent

Matsuda, H.[Hiroyuki], Hirota, Y.[Yuki], Kurihara, K.[Kiyofumi], Tochigi, K.[Katsumi], Ochi, K.[Kenji]

ABSTRACT