Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Isobaric vapor liquid equilibrium (VLE) for pinane, dihydromyrcene (DHM) and dihydromyrcenol (DHMOH) at 6 kPa

Wang, Y.[Yingshu], Guo, C.[Chuan], Liu, X.[Xiaoqin], Huang, S.[Shuicheng], Wang, B.[Biyu], Zheng, H.[Huidong]
Fluid Phase Equilib. 2013, 342, 47-51
ABSTRACT
The isobaric VLE data for three binary systems (DHM + pinane, DHM + DHMOH, pinane + DHMOH) and one ternary system (pinane + DHM + DHMOH) at 6 kPa were measured with a Rose-Williams still. The binary VLE data were correlated with the Wilson and NRTL models. With the obtained model parameters, the ternary (pinane + DHM + DHMOH) VLE data was predicted and compared with the experimental data and the result shows that the parameters also have a good performance in the prediction of the ternary VLE data.
Compounds
# Formula Name
1 C10H18 3,7-dimethyl-1,6-octadiene
2 C10H18 [1S-(1.alpha.,2.beta.,5.alpha.)]-2,6,6-trimethylbicyclo[3.1.1]heptane
3 C10H20O 2,6-dimethyl-7-octen-2-ol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Ebulliometric method (Recirculating still)
  • 13
  • POMD
  • 1
  • 2
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 13
  • POMD
  • 1
  • 3
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Ebulliometric method (Recirculating still)
  • 13
  • POMD
  • 1
  • 3
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 13
  • POMD
  • 2
  • 3
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Ebulliometric method (Recirculating still)
  • 17
  • POMD
  • 2
  • 3
  • Mole fraction - 2 ; Gas
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 17
  • POMD
  • 1
  • 2
  • 3
  • Mole fraction - 2 ; Liquid
  • Mole fraction - 2 ; Gas
  • Mole fraction - 1 ; Gas
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Chromatography
  • Chromatography
  • Chromatography
  • 16