Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

ABSTRACT

Isobaric vapor liquid equilibrium (VLE) data for 2-propanol + 1-butanol, 2-propanol + 1-pentanol, 1- butanol + 1-pentanol and 2-propanol + 1-butanol + 1-pentanol were measured at 101.3 kPa by using an improved Rose still. All the binary VLE data have passed the traditional area test proposed by Herington. The interaction parameters for the Wilson, NRTL and UNIQUAC equations were determined by regressing the binary VLE data. The prediction for ternary system was given by using the three pairs of binary parameters correlated. And the ternary data predicted agreed well with the experiment data.