Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Measurements of H2S solubility in aqueous diisopropanolamine solutions and vapour pressure of diisopropanolamine

Uusi-Kyyny, P.[Petri], Dell'Era, C.[Claudia], Penttila, A.[Anne], Pakkanen, M.[Minna], Alopaeus, V.[Ville]
Fluid Phase Equilib. 2013, 338, 164-171
ABSTRACT
Phase equilibrium measurements were conducted for H2S + water + diisopropanolamine (DIPA) systems with a static total pressure method. The measured systems had DIPA mass fractions from 0.10 to 0.35. Each DIPA solution was measured at several temperatures ranging from 322 K to 353 K. The measurements were successfully described with an electrolyte NRTL-model that was earlier presented in the literature even at the lowest DIPA mass fractions. The vapour pressure of pure DIPA was measured with a distillation method within a temperature range from 420 K to 465 K. An Antoine equation for the vapour pressure of pure DIPA is proposed based on measurements from this work and from the literature. Also an expression for the density of water + DIPA solutions was developed using measurements found in the literature.
Compounds
# Formula Name
1 H2O water
2 H2S hydrogen sulfide
3 C6H15NO2 N-(2-hydroxypropyl)-2-hydroxy-1-propanamine
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Distillation
  • 33
  • POMD
  • 3
  • 1
  • 2
  • Vapor or sublimation pressure, kPa ; Gas
  • Mass fraction - 2; Liquid
  • Mass fraction - 3; Liquid
  • Temperature, K; Gas
  • Gas
  • Liquid
  • Closed cell (Static) method
  • 111
  • POMD
  • 3
  • 1
  • Vapor or sublimation pressure, kPa ; Gas
  • Temperature, K; Gas
  • Mass fraction - 3; Liquid
  • Gas
  • Liquid
  • Closed cell (Static) method
  • 7