Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Solubilities of D-xylose in water + (acetic acid or propionic acid ) mixtures at atmospheric pressure and different temperatures

Li, T.[Tao], Jiang, Z.[Zhenxi], Chen, F.[Feixiong], Ren, B.[Baozeng]
Fluid Phase Equilib. 2012, 333, 13-17
ABSTRACT
Using dynamic method and the laster monitoring observation technique, the solubility of D-xylose in water + acetic acid, and water + propionic acid were measured over the temperature range from (296.65 to 325.45) K at atmospheric pressure. The solubility data of D-xylose in the mixtures of water + acetic acid, and water + propionic acid was found to increase with increasing temperature and decrease with increasing volume fractions of acetic acid, and propionic acid in aqueous solution. The experimental data were correlated by using the Apelblat equation, the lambda-h equation and the ideal equation. The results showed that these three models agreed well with the experimental data, and the Apelblat equation was found to regress the solubility data better than the other two models. The standard enthalpy, standard entropy, and Gibb free energy change of solution of D-xylose were calculated from the solubility data by using the Apelblat model.
Compounds
# Formula Name
1 C2H4O2 acetic acid
2 C3H6O2 propanoic acid
3 H2O water
4 C5H10O5 D-xylose
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 4
  • 1
  • 3
  • Mole fraction - 4 ; Liquid
  • Temperature, K; Liquid
  • Solvent: Volume fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 4
  • synthetic method
  • 75
  • POMD
  • 4
  • 2
  • 3
  • Mole fraction - 4 ; Liquid
  • Temperature, K; Liquid
  • Solvent: Volume fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 4
  • synthetic method
  • 82