ABSTRACT

Liquid liquid equilibrium (LLE) data for the ternary systems (heptane + p-xylene + 1-ethyl-3-methylpyridinium ethylsulfate) and (n-octane + p-xylene + 1-ethyl-3-methylpyridinium ethylsulfate) were measured at T = 313.15 K and atmospheric pressure. The selectivity and aromatic distribution coefficients, calculated from the equilibrium data, were used to determine if this ionic liquid can be used as a potential extracting solvent for the separation of p-xylene from heptane and n-octane. The consistency of tie-line data was ascertained by applying the Othmer-Tobias and Hand equations.

Compounds

#	Formula	Name
1	C7H16	heptane
2	C8H18	octane
3	C8H10	1,4-dimethylbenzene
4	C10H17NO4S	1-ethyl-3-methylpyridinium ethylsulfate

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	3 1 4	Mole fraction - 1 ; Liquid mixture 1 Mole fraction - 1 ; Liquid mixture 2 Mole fraction - 3 ; Liquid mixture 2	Mole fraction - 3; Liquid mixture 1	Temperature, K; Liquid mixture 2 Pressure, kPa; Liquid mixture 2	Liquid mixture 1 Liquid mixture 2	NMR NMR NMR	9
POMD	3 2 4	Mole fraction - 2 ; Liquid mixture 1 Mole fraction - 2 ; Liquid mixture 2 Mole fraction - 3 ; Liquid mixture 2	Mole fraction - 3; Liquid mixture 1	Temperature, K; Liquid mixture 2 Pressure, kPa; Liquid mixture 2	Liquid mixture 1 Liquid mixture 2	NMR NMR NMR	9

Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Liquid-liquid equilibrium (LLE) data for ternary mixtures of {aliphatic + p-xylene + [EMpy][ESO4]} at T = 313.15 K

Kamankesh, A., Vossoughi, M., Shamloo, A., Mirkhani, S. A., Akbari, J.

ABSTRACT