Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Solid-liquid phase equilibrium for the ternary system urea phosphate + ammonium dihydrogen phosphate + water at 25 and 55 .C

Yang, Z.[Zhaopeng], Li, J.[Jun], Luo, J.[Jianhong], Wang, P.[Pan], Zhou, K.[Kun]
Fluid Phase Equilib. 2012, 335, 60-63
ABSTRACT
The ternary system of urea phosphate + ammonium dihydrogen phosphate + water at 25 and 55 C was investigated by the method of isothermal solution saturation and moist residues. Solubility and density data of the system were determined experimentally, and corresponding phase diagrams were constructed on the basis of solubility data. The solid phase in this system was comfirmed by Schreinemaker's method of wet residue. The trajectories at different temperatures are approximately similar, and the crystallization regions of urea phosphate and ammonium dihydrogen phosphate increase as the temperature decreases. The solubility data, density, and the phase equilibrium diagrams for the ternary system can provide the fundamental basis for the preparation of urea phosphate in ammonium dihydrogen phosphate and urea phosphate aqueous mixtures.
Compounds
# Formula Name
1 CH7N2O5P urea phosphate
2 H6NO4P ammonium dihydrogen phosphate
3 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • 3
  • Mass fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Schreinemaker's method of wet residues
  • 16
  • POMD
  • 1
  • 2
  • 3
  • Mass fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal of intercomponent compound 1
  • Schreinemaker's method of wet residues
  • 11
  • POMD
  • 1
  • 2
  • 3
  • Mass fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Schreinemaker's method of wet residues
  • 15
  • POMD
  • 1
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Mass fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • PYCNOM:airbuo
  • 42
  • POMD
  • 2
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • PYCNOM:airbuo
  • 2
  • POMD
  • 2
  • 3
  • Mass fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Schreinemaker's method of wet residues
  • 2
  • POMD
  • 1
  • 3
  • Mass fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Schreinemaker's method of wet residues
  • 2
  • POMD
  • 1
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mass fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • PYCNOM:airbuo
  • 2