Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Solubility of triclosan and iodopropynyl butylcarbamate in pure alkanols at several temperatures

Lim, J.[Junhyuk], Jang, S.[Sunghyun], Shin, M. S.[Moon Sam], Kim, H.[Hwayong]
Fluid Phase Equilib. 2012, 332, 144-150
ABSTRACT
Solubility data for triclosan and iodopropynyl butylcarbamate (IPBC) in ethanol, 1-propanol, 1-butanol, 1-pentanol, 1-hexanol, and 1-heptanol were measured. Solid liquid phase equilibrium measurements were conducted at several temperatures (from 278.15 to 318.15 K). After drying the equilibrium saturated solutions, gravimetric measurement was used to determine experimental solubility. The data were correlated using a equation for the solubility of a solid in a liquid and the nonrandom two liquid (NRTL), universal quasi-chemical (UNIQUAC) and Wilson models for activity coefficients. The data are well fitted with all three models for the six pure alcohols studied here.
Compounds
# Formula Name
1 C12H7Cl3O2 2,4,4'-trichloro-2'-hydroxydiphenyl ether
2 C8H12INO2 iodopropynyl butylcarbamate
3 C2H6O ethanol
4 C3H8O propan-1-ol
5 C4H10O butan-1-ol
6 C5H12O pentan-1-ol
7 C6H14O hexan-1-ol
8 C7H16O heptan-1-ol
9 H2O water
10 C3H7NO2 DL-2-aminopropanoic acid
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 10
  • 9
  • Mole fraction - 10 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 10
  • Phase equilibration
  • 6
  • POMD
  • 3
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Phase equilibration
  • 5
  • POMD
  • 4
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Phase equilibration
  • 5
  • POMD
  • 5
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Phase equilibration
  • 5
  • POMD
  • 6
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Phase equilibration
  • 5
  • POMD
  • 7
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Phase equilibration
  • 5
  • POMD
  • 8
  • 1
  • Mole fraction - 1 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 1
  • Phase equilibration
  • 5
  • POMD
  • 3
  • 2
  • Mole fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Phase equilibration
  • 5
  • POMD
  • 4
  • 2
  • Mole fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Phase equilibration
  • 5
  • POMD
  • 5
  • 2
  • Mole fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Phase equilibration
  • 5
  • POMD
  • 6
  • 2
  • Mole fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Phase equilibration
  • 5
  • POMD
  • 7
  • 2
  • Mole fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Phase equilibration
  • 5
  • POMD
  • 8
  • 2
  • Mole fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Crystal - 2
  • Phase equilibration
  • 5