The critical temperatures and the critical pressures of ferrocene, butylferrocene, benzoylferrocene, and 1-acetylferrocene have been measured. All the compounds studied begin to decompose at temperatures below their critical points. A method of pulse heating applicable to thermally unstable compounds has been used. Residence times were from (0.03 to 1.0) ms, which resulted in little decomposition of the substances in the course of measuring. The contributions of the groups Fe-CH and Fe-C for the estimation of the critical properties of ferrocene derivatives by the method of Marrero and Gani have been determined from the experimental data.
Compounds
#
Formula
Name
1
C10H10Fe
ferrocene
2
C14H18Fe
butylferrocene
3
C12H12FeO
acetylferrocene
4
C17H14FeO
benzoylferrocene
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.