ABSTRACT

New experimental excess molar enthalpy data (304 points) of the binary systems dibutyl ether (DBE) or 1-butanol and 1-hexene, or methylcyclohexane or toluene at 298.15K and 313.15 K, and DBE or 1-butanol and cyclohexane or 2,2,4-trimethylpentane (TMP) at 313.15K at atmospheric pressure are reported. A quasi-isothermal flow calorimeter has been used to make the measurements. All the binary systems show endothermic character except the system DBE + 1-hexene at both temperatures. The experimental data for the binary systems have been fitted using the Redlich-Kister rational equation. The values of the standard deviation indicate good agreement between the experimental results and those calculated from the equations.

Compounds

#	Formula	Name
1	C8H18O	dibutyl ether
2	C4H10O	butan-1-ol
3	C6H12	hex-1-ene
4	C6H12	cyclohexane
5	C7H14	methylcyclohexane
6	C7H8	toluene
7	C8H18	2,2,4-trimethylpentane

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1 3	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Flow calorimetry	37
POMD	5 1	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Flow calorimetry	38
POMD	6 1	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Temperature, K; Liquid Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid	Flow calorimetry	38
POMD	2 3	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Temperature, K; Liquid Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid	Flow calorimetry	38
POMD	2 5	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Temperature, K; Liquid Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid	Flow calorimetry	38
POMD	2 6	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Temperature, K; Liquid Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid	Flow calorimetry	38
POMD	4 1	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Flow calorimetry	19
POMD	1 7	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Flow calorimetry	19
POMD	2 4	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Mole fraction - 4; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Flow calorimetry	19
POMD	2 7	Excess molar enthalpy (molar enthalpy of mixing), kJ/mol ; Liquid	Mole fraction - 7; Liquid	Pressure, kPa; Liquid Temperature, K; Liquid	Liquid	Flow calorimetry	19

Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Ether + alcohol + hydrocarbon mixtures in fuels and bio-fuels: Excess enthalpies of binary mixtures containing dibutyl ether (DBE) or 1-butanol and 1-hexene or methylcyclohexane or toluene or cyclohexane or 2,2,4-trimethylpentane at 298.15K and 313.15K

Aguilar, F.[Fernando], Alaoui, F. E. M.[Fatima E. M.], Segovia, J. J.[Jose J.], Villamanan, M. A.[Miguel A.], Montero, E. A.[Eduardo A.]

ABSTRACT