Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

ABSTRACT

The amount of available accurate experimental data on the surface tension of ionic liquids is still limited; in many cases the data are rare or even absent. In the present study, air liquid interfacial tension data were determined experimentally for five 1-Cn-3-methylimidazolium based ionic liquids (n=2, 4, and 6), three with trifluoromethanesulfonate and two with tetrafluoroborate anion, at atmospheric pressure in the temperature range from 268 to 356 K. The resultant surface tension data are average values of the measurements repeated many times at each set point temperature. The accuracy of the results, was confirmed by employing the Wilhelmy plate and the du Nouy ring methods in parallel, using the Kruss K100MK2 tensiometer. For the Wilhelmy plate data the combined standard uncertainty is estimated to be about 0.05 mN m-1. The data obtained by du Nouy method show about up to seven times greater scatter than those obtained by the Wilhelmy plate method. To the 50 up to now published surface tension values for the five studied ionic liquids the present study adds further 175 data points. In contrast to that of n-alkanes, the surface tension of 1-alkyl-3-methylimidazolium based ionic liquids decreases and their surface entropy increases with the cation alkyl chain length.