Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Equilibrium solubility of carbon dioxide in 2(methylamino)ethanol

Haider, H.[Hawar], Yusoff, R.[Rozita], Aroua, M. K.[Mohammed Kheireddine]
Fluid Phase Equilib. 2011, 303, 2, 162-167
ABSTRACT
In this paper the equilibrium solubility of carbon dioxide in 1.0 M, 2.0 Mand 4.0 M 2(methylamino)ethanol (MAE) is measured at 303, 313 and 333 K, and at CO2 partial pressures ranging from 1 to 100 kPa using stirred cell reactor. The Kent-Eisenberg model was used to predict the solubility of carbon dioxide in MAE solutions. The equilibrium constant representing hydrolysis of carbamate ion is correlated with temperature, CO2 partial pressure and amine concentration by non-linear regression, using experimental results of carbamate ion concentrations. The model predicted results showed good agreement with the experimental solubility results. The solubility profile of CO2 in MAE showed better performance when compared with other commercial amines.
Compounds
# Formula Name
1 C3H9NO 2-(methylamino)ethanol
2 CO2 carbon dioxide
3 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • 3
  • Mole fraction - 2 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa - 2; Gas
  • Solvent: Amount concentration (molarity), mol/dm3 - 1; Liquid
  • Liquid
  • Gas
  • Titration method
  • 28