Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Liquid-liquid equilibria of ternary mixtures of dimethyl carbonate, diphenyl carbonate, phenol and water at 358.15 K

Hwang, I.-C.[In-Chan], Park, S. J.[So Jin]
Fluid Phase Equilib. 2011, 301, 1, 18-21
ABSTRACT
The ternary liquid-liquid equilibria (LLE) of the following systems were analytically determined at 358.15 K at atmospheric pressure using stirred and thermo-regulated cells: {dimethyl carbonate (DMC) + diphenyl carbonate (DPC) + water}, {DMC + phenol + water} and {DPC + phenol + water}. The experimental ternary LLE data were correlated with the NRTL and UNIQUAC activity coefficient models. Additionally, the Bachman-Brown correlation was used to ascertain the reliability of the experimental data for each system.
Compounds
# Formula Name
1 C3H6O3 dimethyl carbonate
2 H2O water
3 C13H10O3 diphenyl carbonate
4 C6H6O phenol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 3
  • 1
  • 2
  • Mole fraction - 3 ; Liquid mixture 1
  • Mole fraction - 3 ; Liquid mixture 2
  • Mole fraction - 1 ; Liquid mixture 2
  • Mole fraction - 1; Liquid mixture 1
  • Temperature, K; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 1
  • Liquid mixture 2
  • Chromatography
  • Chromatography
  • Chromatography
  • 8
  • POMD
  • 4
  • 1
  • 2
  • Mole fraction - 4 ; Liquid mixture 1
  • Mole fraction - 4 ; Liquid mixture 2
  • Mole fraction - 1 ; Liquid mixture 2
  • Mole fraction - 1; Liquid mixture 1
  • Temperature, K; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 1
  • Liquid mixture 2
  • Chromatography
  • Chromatography
  • Chromatography
  • 6
  • POMD
  • 3
  • 4
  • 2
  • Mole fraction - 3 ; Liquid mixture 2
  • Mole fraction - 4 ; Liquid mixture 1
  • Mole fraction - 3 ; Liquid mixture 1
  • Mole fraction - 4; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 2
  • Temperature, K; Liquid mixture 2
  • Liquid mixture 2
  • Liquid mixture 1
  • Chromatography
  • Chromatography
  • Chromatography
  • 7