Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Isothermal vapor-liquid equilibrium data for the binary mixture difluoromethane (HFC-32)+ ethyl fluoride (HFC-161) over a temperature range from 253.15 to 303.15 K

Han, X. H., Gao, Z. J., Xu, Y. J., Qiu, Y., Ming, X. W., Wang, Q., Chen, G. M.
Fluid Phase Equilib. 2010, 299, 1, 116-121
ABSTRACT
Isothermal vapor-liquid equilibrium data of difluoromethane (HFC-32) +ethyl fluoride (HFC-161) mixture in the range of temperatures 253.15 K to 303.15 K have been measured in the wide range of compositions. The experimental method used for this work is the single-cycle type. Using Peng-Robinson (PR) equation of state, combined with the first Modified Huron-Vidal (MHV1) mixing rule and Wilson model, the vapor-liquid equilibrium data are correlated. The correlation results have a good agreement with the experiment results. The average absolute vapor composition deviation is within 0.0125, and its largest absolute deviation of the vapor composition is 0.0568; the average relative pressure deviation is within 0.76 % and its largest relative pressure deviation is 2.87 %. In addition, the results reveal that there is no azeotrope in the binary system, and their temperature glides are small.
Compounds
# Formula Name
1 CH2F2 difluoromethane
2 C2H5F fluoroethane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Ebulliometric method (Recirculating still)
  • 96
  • POMD
  • 1
  • 2
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 96