Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Bubble point measurements of binary mixtures formed by 1-hexanol with selected nitro-compounds and substituted benzenes at 95.6 kPa

Reddy, K. S., Swamy, A. V. N., Prasad, T. E. V.[T. E. Vittal], Prasad, D. H. L.
Fluid Phase Equilib. 2010, 298, 2, 276-279
ABSTRACT
Bubble point measurements (at 95.6 kPa) over the entire composition range are carried out for the binary mixtures formed by 1-hexanol with the: nitro-compounds (acetonitrile, acrylonitrile N,N-dimethyl formamide and aniline) and substituted benzenes (o-xylene, chlorobenzene, and nitrobenzene), employing a Swietoslawski type ebulliometer. Wilson model is found to represent the measured liquid phase composition versus bubble point temperature data well. Computed values of the vapor phase mole fractions and liquid phase activity coefficients are tabulated and briefly discussed.
Compounds
# Formula Name
1 C6H14O hexan-1-ol
2 C2H3N acetonitrile
3 C3H3N acrylonitrile
4 C3H7NO dimethylformamide
5 C6H7N aniline
6 C6H5Cl chlorobenzene
7 C6H5NO2 nitrobenzene
8 C8H10 1,2-dimethylbenzene
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 1
  • POMD
  • 2
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 1
  • POMD
  • 3
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 1
  • POMD
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 1
  • POMD
  • 5
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 1
  • POMD
  • 6
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 1
  • POMD
  • 7
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 1
  • POMD
  • 8
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Pycnometric method
  • 1
  • POMD
  • 2
  • 1
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Ebulliometric method (Recirculating still)
  • 15
  • POMD
  • 2
  • 1
  • Mole fraction - 2 ; Gas
  • Mole fraction - 2; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 15
  • POMD
  • 3
  • 1
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Ebulliometric method (Recirculating still)
  • 15
  • POMD
  • 3
  • 1
  • Mole fraction - 3 ; Gas
  • Mole fraction - 3; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 15
  • POMD
  • 4
  • 1
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Ebulliometric method (Recirculating still)
  • 16
  • POMD
  • 4
  • 1
  • Mole fraction - 4 ; Gas
  • Mole fraction - 4; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 16
  • POMD
  • 5
  • 1
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Ebulliometric method (Recirculating still)
  • 15
  • POMD
  • 5
  • 1
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 15
  • POMD
  • 6
  • 1
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 6; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Ebulliometric method (Recirculating still)
  • 16
  • POMD
  • 6
  • 1
  • Mole fraction - 6 ; Gas
  • Mole fraction - 6; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 16
  • POMD
  • 7
  • 1
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Ebulliometric method (Recirculating still)
  • 16
  • POMD
  • 7
  • 1
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 16
  • POMD
  • 8
  • 1
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 8; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Ebulliometric method (Recirculating still)
  • 16
  • POMD
  • 8
  • 1
  • Mole fraction - 8 ; Gas
  • Mole fraction - 8; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 16