Isothermal vapor-liquid equilibrium data for the binary mixture ethyl fluoride (HFC-161) + 1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea) over a temperature range from 253.15 K to 313.15 K
Vapor-liquid equilibrium (VLE) data for the refrigerant mixture ethyl fluoride (HFC-161) + 1,1,1,2,3,3,3-heptafluoropropane (HFC-227ea) are reported in the temperature range from 253.15 K to 313.15 K with a single-phase circulation vapor-liquid equilibrium still. The results of the correlation for the vapor-liquid equilibrium data with Peng Robinson (PR) equation of state (EOS), combined with the first Modified Huron-Vidal (MHV1) mixing rule and Wilson model, are presented. These results are in a good agreement with experimental data. The average and maximum derivations of vapor mole fraction composition are within 0.0130 and 0.0295 respectively, and the average and maximum relative derivations of pressure are within 1.04 % and 2.96 %, respectively. The model parameters, determined from these binary data, are given to predict the phase behavior for a later ternary system. The binary system HFC-161 + HFC-227ea is a non-azeotropic mixture and exhibits a negative deviation from Raoult's law.
Compounds
#
Formula
Name
1
C2H5F
fluoroethane
2
C3HF7
1,1,1,2,3,3,3-heptafluoropropane
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.