Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Isobaric vapor-liquid equilibria for water + n-propanol + n-butanol ternary system at atmospheric pressure

Wei, S.[Shun'an], Zhang, J.[Jianhua], Dong, L.[Lichun], Tan, S.[Shiyu], Wang, P.[Pan], Fu, X.[Xuemei], Qi, Y.[Yongli]
Fluid Phase Equilib. 2010, 297, 1, 72-76
ABSTRACT
Isobaric vapor-liquid equilibrium (VLE) data for water + n-propanol + n-butanol ternary system have been extensively measured at 99.2 kPa using a recirculating still. The experimental data were then correlated using the extended UNIQUAC model, in which the binary interaction energy parameters between the three components were obtained through a simplex fitting method. The results showed that the calculated data by the extended UNIQUAC model using the same interaction energy parameters agree well with both the experimental data and the literature data. It demonstrated that the experimental data are very consistent with the literature data; and the extended UNIQUAC model is reliable to predict the VLE of the ternary system using the obtained interaction energy parameters.
Compounds
# Formula Name
1 H2O water
2 C3H8O propan-1-ol
3 C4H10O butan-1-ol
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 3
  • 1
  • Mole fraction - 2 ; Liquid
  • Mole fraction - 2 ; Gas
  • Mole fraction - 1 ; Gas
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Chromatography
  • Chromatography
  • Chromatography
  • 53