Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

High-pressure vapor-liquid equilibria for carbon dioxide + tetrahydrofuran mixtures

Kodama, D.[Daisuke], Yagihashi, T.[Takuya], Hosoya, T.[Tetsuya], Kato, M.[Masahiro]
Fluid Phase Equilib. 2010, 297, 2, 168-171
ABSTRACT
Vapor-liquid equilibria and saturated density for carbon dioxide + tetrahydrofuran mixtures at high pressures were measured by the analytical method at the temperatures 298.15 and 313.15 K. The experimental apparatus equipped with three Anton Paar DMA 512S vibrating tube density meters was previously developed for measuring vapor-liquid-liquid equilibrium at high pressures. The equilibrium composition and saturated density of each phase were determined by gas chromatograph and vibrating tube density meters, respectively. The bubble point pressure at the temperature 313.15 K was further measured by the synthetic method. The experimental data were correlated with Soave-Redlich-Kwong (SRK) equation of state and the pseudocubic equation of state.
Compounds
# Formula Name
1 CO2 carbon dioxide
2 C4H8O tetrahydrofuran
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • Ebulliometric method (Recirculating still)
  • 15
  • POMD
  • 2
  • 1
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Gas
  • Vibrating tube method
  • 15
  • POMD
  • 2
  • 1
  • Mass density, kg/m3 ; Gas
  • Temperature, K; Gas
  • Mole fraction - 1; Gas
  • Gas
  • Liquid
  • Vibrating tube method
  • 15
  • POMD
  • 2
  • 1
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Temperature, K; Liquid
  • Gas
  • Liquid
  • Chromatography
  • 15