ABSTRACT

Measurement of heat capacities Cp at 308.65, 311.65 and 314.65 K have been made for solutions of tetraphenyl phosphonium chloride (TPPC) with methanol, ethanol, acetonitrile and water for dilute solutions (up to 0.1 M) by means of a microcalorimeter (Setaram C-80, model from France). The experimental values of heat capacity for the various solutions have been used to calculate the values of partial molar heat capacities Cp2,m of the salt in different solutions. The results are studied in relation to the special features of solvations in solutions of the TPPC.

Compounds

#	Formula	Name
1	C24H20ClP	tetraphenylphosphonium chloride
2	C2H6O	ethanol
3	CH4O	methanol
4	C2H3N	acetonitrile
5	H2O	water

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	3 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Amount concentration (molarity), mol/dm3 - 1; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:16	18
POMD	3 1	Specific heat capacity at constant pressure, J/K/kg ; Liquid	Temperature, K; Liquid Amount concentration (molarity), mol/dm3 - 1; Liquid	Pressure, kPa; Liquid	Liquid	heat flux microcalorimetry	18
POMD	2 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Amount concentration (molarity), mol/dm3 - 1; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:16	18
POMD	2 1	Specific heat capacity at constant pressure, J/K/kg ; Liquid	Temperature, K; Liquid Amount concentration (molarity), mol/dm3 - 1; Liquid	Pressure, kPa; Liquid	Liquid	heat flux microcalorimetry	18
POMD	4 1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Amount concentration (molarity), mol/dm3 - 1; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:16	18
POMD	4 1	Specific heat capacity at constant pressure, J/K/kg ; Liquid	Temperature, K; Liquid Amount concentration (molarity), mol/dm3 - 1; Liquid	Pressure, kPa; Liquid	Liquid	heat flux microcalorimetry	18
POMD	1 5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Amount concentration (molarity), mol/dm3 - 1; Liquid	Pressure, kPa; Liquid	Liquid	VIBTUB:UFactor:16	18
POMD	1 5	Specific heat capacity at constant pressure, J/K/kg ; Liquid	Temperature, K; Liquid Amount concentration (molarity), mol/dm3 - 1; Liquid	Pressure, kPa; Liquid	Liquid	heat flux microcalorimetry	18

Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Heat capacities of tetraphenyl phosphonium chloride in methanol, ethanol, acetonitrile, and water

Tripathi, A. D.[Atri Deo]

ABSTRACT