Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

ABSTRACT

For the first time, results of high-precision measurements of the viscosity coefficient of triethylamine vapor at low densities are reported. The relative measurements with an all-quartz oscillating-disk viscometer were carried out along seven isochores at densities from 0.002 to 0.009 mol m-3 in the temperature range between 298 and 498 K. The uncertainty is estimated to be +-0.2% at ambient temperature, increasing up to +-0.3% at higher temperatures. First isothermal values were recalculated from the original experimental data and then evaluated with a first-order expansion for the viscosity, in terms of density. In addition, viscosity values of the saturated vapor were determined at low temperatures. The results are utilized to model the viscosity coefficient of triethylamine vapor at moderately low densities. A so-called individual correlation on the basis of the extended theorem of corresponding states was employed to describe the zero-density viscosity coefficient, whereas the Rainwater Friend theory was used to represent the initial density dependence expressed as second viscosity virial coefficient.