Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Alkylsulfate-based ionic liquids to separate azeotropic mixtures

Pereiro, A. B., Deive, F. J., Esperanca, J. M. S. S., Rodriguez, A.
Fluid Phase Equilib. 2010, 291, 1, 13-17
ABSTRACT
The knowledge of liquid-liquid equilibria (LLE) of the ternary systems (hexane or heptane + ethanol + 1-ethyl-3- methylimidazolium ethylsulfate (EMIM EtSO4)) is essential for the separation of alkanes from their azeotropic mixtures with ethanol. The experimental LLE has been determined at 298.15 K and atmospheric pressure. Experimental LLE are correlated using NRTL equation. The solvent capacity of the IL is compared with others aiming to analyze the efficiency of these molten salts used as entrainers. The extraction processes with this IL are simulated using a conventional software. A comparison of the alkylsulfate-based ILs ability for the extraction process, determined from the simulation results, is enclosed.
Compounds
# Formula Name
1 C6H14 hexane
2 C7H16 heptane
3 C2H6O ethanol
4 C8H16N2O4S 1-ethyl-3-methylimidazolium ethyl sulfate
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 4
  • Refractive index (Na D-line) ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Standard Abbe refractometry
  • 1
  • POMD
  • 4
  • Mass density, kg/m3 ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Vibrating tube method
  • 1
  • POMD
  • 3
  • 1
  • 4
  • Mole fraction - 1 ; Liquid mixture 1
  • Mole fraction - 1 ; Liquid mixture 2
  • Mole fraction - 3 ; Liquid mixture 2
  • Mole fraction - 3; Liquid mixture 1
  • Temperature, K; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 1
  • Liquid mixture 2
  • Density calibration data
  • Density calibration data
  • Density calibration data
  • 11
  • POMD
  • 3
  • 2
  • 4
  • Mole fraction - 2 ; Liquid mixture 2
  • Mole fraction - 2 ; Liquid mixture 1
  • Mole fraction - 3 ; Liquid mixture 1
  • Mole fraction - 3; Liquid mixture 2
  • Temperature, K; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 2
  • Liquid mixture 1
  • Density calibration data
  • Density calibration data
  • Density calibration data
  • 12