ABSTRACT

Viscosities and densities of d-glucose.water mixtureswere measured, and conductivities in the NiSO4.dglucose. water systemwere also measured at 278.15.308.15K in 5K intervals. Based on the Lee.Wheaton conductivity equation, values of limiting molar conductivities 0 and association constants KA were obtained. Changes in the standard thermodynamic functions, Gibbs energy G. A(T), enthalpy H. A(T), and entropy S. A(T), for a process of ion-pair formation were calculated at different temperatures. The results show that (1) at given temperatures, the 0 values for 1/2NiSO4 decrease with increasing concentrations of d-glucose; (2) at fixed concentrations of d-glucose, the 0 values for 1/2NiSO4 increase with increasing temperature; and (3) the process of association of NiSO4 is controlled by the change in entropy S. A.

Compounds

#	Formula	Name
1	C6H12O6	D-glucose
2	H2O	water
3	NiO4S	nickel monosulfate

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1 2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid Molality, mol/kg - 1; Liquid	Pressure, kPa; Liquid	Liquid	Capillary tube (Ostwald; Ubbelohde) method	42
POMD	1 2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Molality, mol/kg - 1; Liquid	Pressure, kPa; Liquid	Liquid	Vibrating tube method	42
POMD	1 2 3	Molar conductivity, S*m2/mol ; Liquid	Temperature, K; Liquid Molality, mol/kg - 3; Liquid Solvent: Molality, mol/kg - 1; Liquid	Pressure, kPa; Liquid	Liquid	Direct current cell with electrodes	294

Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Conductivity in NiSO4 d-glucose water solutions at 278.15 308.15K

Zhuo, K.[Kelei], Liu, Y.[Yaohui], Liu, H.[Hongxun], Wang, J.[Jianji]

ABSTRACT