ABSTRACT

Bubble-point vapor pressures, equilibrium temperatures and flash points for binary mixtures of a high energy density hydrocarbon fuel, tricyclo [5.2.1.0^(2.6)] decane (JP-10), and dimethyl carbonate (DMC) were measured. Correlation between vapor pressures and equilibrium temperatures for each mixture was given by the Antoine equation. The binary system of JP-10 and DMC appears with very large positive deviations of vapor pressure from the Raoult's law. The experimental vapor pressures are correlated and the flash points are then predicted using Scatchard-Hildeband, Van Laar and Wilson models of liquid phase activity coefficients with satisfactory results

Compounds

#	Formula	Name
1	C10H16	exo-tetrahydrodicyclopentadiene
2	C3H6O3	dimethyl carbonate

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Phase	Method	#Points
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	UNKNOWN	1
POMD	1	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Liquid Air at 1 atmosphere	UNKNOWN	1
POMD	1	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Twin ebulliometer	15
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	UNKNOWN	1
POMD	2	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid	Liquid Gas	Twin ebulliometer	15
POMD	2	Viscosity, Pa*s ; Liquid	Temperature, K; Liquid	Liquid Air at 1 atmosphere	UNKNOWN	1
POMD	2 1	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid Mole fraction - 2; Liquid	Liquid Gas	Twin ebulliometer	150

Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Vapor pressures and flash points for binary mixtures of tricyclo [5.2.1.0^(2.6)] decane and dimethyl carbonate

Xing, Y.[Yan], Shao, D.[Dongbei], Fang, W.[Wenjun], Guo, Y.[Yongsheng], Lin, R.[Ruisen]

ABSTRACT