Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Liquid liquid equilibria and vapor liquid equilibria for the binary system of epichlorohydrin and water

Yue, Q.[Qun], Zhu, J.-W.[Jia-Wen], Wu, Y.-Y.[Yan-Yang], Yuan, X.-q.[Xiang-qian], Ma, L.[Liang]
Fluid Phase Equilib. 2009, 283, 1-2, 12-16
ABSTRACT
The liquid liquid equilibria (LLE) data and vapor liquid equilibria (VLE) data for the binary system of epichlorohydrin (EPCH) +water were studied at 101.3 kPa. An azeotropic behavior has been found in the EPCH +water. Both the experimental LLE and VLE datawere compared with the correlated values obtained by means of the NRTL and UNIQUAC equations. Both models satisfactorily correlated the experimental data. Thermodynamic consistency has been tested for the VLE data.
Compounds
# Formula Name
1 C3H5ClO 1-chloro-2,3-epoxypropane
2 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Activity coefficient - 1 ; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Chromatography
  • 27
  • POMD
  • 1
  • 2
  • Activity coefficient - 2 ; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Chromatography
  • 27
  • POMD
  • 1
  • 2
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • Ebulliometric method (Recirculating still)
  • 27
  • POMD
  • 1
  • 2
  • Mole fraction - 1 ; Liquid mixture 2
  • Temperature, K; Liquid mixture 2
  • Pressure, kPa; Liquid mixture 2
  • Liquid mixture 2
  • Liquid mixture 1
  • Chromatography
  • 13
  • POMD
  • 1
  • 2
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Gas
  • Gas
  • Liquid
  • Chromatography
  • 27
  • POMD
  • 1
  • 2
  • Mole fraction - 1 ; Liquid mixture 1
  • Temperature, K; Liquid mixture 1
  • Pressure, kPa; Liquid mixture 1
  • Liquid mixture 1
  • Liquid mixture 2
  • Chromatography
  • 13