Vapour liquid equilibrium measurements for binary and ternary (carbon dioxide + -myrcene and carbon dioxide + -myrcene + hydrogen) systems have been carried out at 323.15K and pressures in the range from 7MPa to the critical pressure of the binary mixture and at pressures from 10 to 14MPa for the investigated ternary systems. Samples from the coexisting phases were taken, and compositions were determined experimentally. Results were correlated using the Peng Robinson and the Soave Redlich Kwong equations of state with the Mathias Klotz Prausnitz mixing rule. The set of interaction parameters for the employed equations of state and applied mixing rule for the system of CO2 + -myrcene and of CO2 + -myrcene +H2 were obtained. Additionally, the volume expansion of the liquid phase for the binary mixtures (carbon dioxide + -myrcene and carbon dioxide + limonene) were measured at 323.15K and at pressures from 4MPa up to very close to the critical pressure of the mixture. The ratio of liquid phase total volumes at the given pressure and at 4MPa was calculated.
Compounds
#
Formula
Name
1
H2
hydrogen
2
CO2
carbon dioxide
3
C10H16
2-methyl-6-methylene-2,7-octadiene
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.