ABSTRACT

Isothermal vapor liquid equilibrium data at 323.15K are reported for the binary systems propyl vinyl ether + 1-propanol, PVE + benzene and 1-propanol + benzene and also for ternary system PVE + 1- propanol + benzene by using headspace gas chromatography. The experimental binary and ternary vapor liquid equilibrium data were correlated with different activity coefficient models. The excess volumes and deviations in molar refractivity data are also reported for the same binary and ternary systems at 298.15 K. These properties are correlated with Redlich Kister equation for binary systems, and with the Cibulka equation for the ternary system, respectively.

Compounds

#	Formula	Name
1	C5H10O	propyl vinyl ether
2	C3H8O	propan-1-ol
3	C6H6	benzene

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	3	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Vibrating tube method	1
POMD	2 1	Vapor or sublimation pressure, kPa ; Liquid	Mole fraction - 1; Gas	Temperature, K; Liquid	Liquid Gas	Calculated	22
POMD	2 1	Refractive index (Na D-line) ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	11
POMD	2 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	11
POMD	2 1	Mole fraction - 1 ; Liquid	Mole fraction - 1; Gas	Temperature, K; Liquid	Liquid Gas	Chromatography	22
POMD	3 1	Vapor or sublimation pressure, kPa ; Liquid	Mole fraction - 1; Gas	Temperature, K; Liquid	Liquid Gas	Calculated	21
POMD	3 1	Refractive index (Na D-line) ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	11
POMD	3 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	11
POMD	3 1	Mole fraction - 1 ; Liquid	Mole fraction - 1; Gas	Temperature, K; Liquid	Liquid Gas	Chromatography	21
POMD	2 3	Vapor or sublimation pressure, kPa ; Liquid	Mole fraction - 2; Gas	Temperature, K; Liquid	Liquid Gas	Calculated	20
POMD	2 3	Refractive index (Na D-line) ; Liquid	Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	11
POMD	2 3	Mass density, kg/m3 ; Liquid	Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	11
POMD	2 3	Mole fraction - 2 ; Liquid	Mole fraction - 2; Gas	Temperature, K; Liquid	Liquid Gas	Chromatography	20
POMD	2 3 1	Refractive index (Na D-line) ; Liquid	Mole fraction - 1; Liquid Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Standard Abbe refractometry	57
POMD	2 3 1	Mass density, kg/m3 ; Liquid	Mole fraction - 1; Liquid Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Vibrating tube method	57
POMD	2 3 1	Mole fraction - 2 ; Gas Mole fraction - 2 ; Liquid Mole fraction - 1 ; Liquid	Pressure, kPa; Liquid Mole fraction - 1; Gas	Temperature, K; Gas	Gas Liquid	Chromatography Chromatography Chromatography	63

Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Isothermal vapor liquid equilibrium at 323.15K and excess molar volumes and refractive indices at 298.15K for the ternary system propyl vinyl ether + 1-propanol + benzene and its binary sub-systems

Kim, H.-D.[Hyeon-Deok], Hwang, I.-C.[In-Chan], Park, S.-J.[So-Jin]

ABSTRACT