ABSTRACT

Bubble-point temperature data at 95.5 kPa, over the entire composition range are obtained for the binary mixtures formed by acrylonitrile with 1,2-dichloroethane, 1,1,2,2-tetrachloroethane, chlorobenzene and nitrobenze. A swietoslawski type ebulliometer is used to measure the bubble point temperatures. The Wilson equation is used to represent the measured liquid phase composition versus temperature data. Computed values of the vapor phase mole fraction, liquid phase activity coefficients and excess Gibbs energy are presented and briefly discussed.

Compounds

#	Formula	Name
1	C3H3N	acrylonitrile
2	C2H4Cl2	1,2-dichloroethane
3	C2H2Cl4	1,1,2,2-tetrachloroethane
4	C6H5Cl	chlorobenzene
5	C6H5NO2	nitrobenzene

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	EBULLIO:UFactor:4	1
POMD	1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid		Liquid Gas	Standard Abbe refractometry	1
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid		Liquid Gas	PYCNOM:UFactor:8	1
POMD	2	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	EBULLIO:UFactor:4	1
POMD	2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid		Liquid Gas	Standard Abbe refractometry	1
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid		Liquid Gas	PYCNOM:UFactor:8	1
POMD	3	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	EBULLIO:UFactor:4	1
POMD	3	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid		Liquid Gas	Standard Abbe refractometry	1
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid		Liquid Gas	PYCNOM:UFactor:8	1
POMD	4	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	EBULLIO:UFactor:4	1
POMD	4	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid		Liquid Gas	Standard Abbe refractometry	1
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid		Liquid Gas	PYCNOM:UFactor:8	1
POMD	5	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	EBULLIO:UFactor:4	1
POMD	5	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid		Liquid Gas	Standard Abbe refractometry	1
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid		Liquid Gas	PYCNOM:UFactor:8	1
POMD	2 1	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid Gas	EBULLIO:UFactor:4	16
POMD	3 1	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid Gas	EBULLIO:UFactor:4	16
POMD	1 4	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid Gas	EBULLIO:UFactor:4	16
POMD	5 1	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 1; Liquid	Pressure, kPa; Liquid	Liquid Gas	EBULLIO:UFactor:4	16

Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Vapor-liquid equilibrium and excess Gibbs energies of some binary mixtures of acrylonitrile at 95.5 kPa

Prasad, T. E. V.[T. E. Vittal], Nath, A. N. V., Prasad, D. H. L.

ABSTRACT