Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Investigation of the aqueous salt solutions of some first and second group metals at various pressures

Filiz, M.[Mehmet], Gulen, J.[Jale]
Fluid Phase Equilib. 2008, 267, 1, 18-22
ABSTRACT
In the scope of this study, boiling points of aqueous solutions ofNaCl, DCl, CaCl2, BaCl2,KNO3 and Ca(NO3)2 salts with salt concentrations between 0.5335 and 6.5935 mol kg-1 within 21.332 101.325 kPa pressure range have been determined. Duhring diagrams have been plotted for each solution. In cases, where Raoult s law applied to non-dilute solutions, the deviations from these were determined.
Compounds
# Formula Name
1 ClNa sodium chloride
2 H2O water
3 CaCl2 calcium chloride
4 BaCl2 barium chloride
5 KNO3 potassium nitrate
6 ClK potassium chloride
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 2
  • Boiling temperature at pressure P, K ; Liquid
  • Molality, mol/kg - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:4
  • 26
  • POMD
  • 2
  • 3
  • Boiling temperature at pressure P, K ; Liquid
  • Molality, mol/kg - 3; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:8
  • 52
  • POMD
  • 2
  • 4
  • Boiling temperature at pressure P, K ; Liquid
  • Molality, mol/kg - 4; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:4
  • 39
  • POMD
  • 2
  • 5
  • Boiling temperature at pressure P, K ; Liquid
  • Molality, mol/kg - 5; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:4
  • 52
  • POMD
  • 6
  • 2
  • Boiling temperature at pressure P, K ; Liquid
  • Molality, mol/kg - 6; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:8
  • 39