Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

ABSTRACT

Solid liquid equilibrium was measured for benzene + cyclohexane, trans-decahydronaphthalene + naphthalene and cis-decahydronaphthalene + naphthalene under the atmospheric pressure in the temperature range from 226.69 to 353.14 K. The apparatus was specially designed in this study, and it was based on a cooling method. The phase diagram with the complete immiscible solids was observed for the three systems, and the eutectic point was found at x2 = 0.2709 and Teu = 232.11K for benzene + cyclohexane, x2 = 0.9816 and Teu = 241.98K for transdecahydronaphthalene + naphthalene, and x3 = 0.9822 and Teu = 225.74K for cis-decahydronaphthalene + naphthalene, respectively. Hydrogen solubilitywas also measured for the two pure substances, trans-decahydronaphthalene and cis-decahydronaphthalene, and the three mixtures, transdecahydronaphthalene + cis-decahydronaphthalene, trans-decahydronaphthalene + naphthalene, and cis-decahydronaphthalene + naphthalene, in the pressure range from 1.702 to 4.473MPa at 303.15 K. Considering the solid liquid equilibrium data, mole ratio of trans-decahydronaphthalene:cis-decahydronaphthalene was set to 50:50, and those of trans-decahydronaphthalene + naphthalene, and cisdecahydronaphthalene + naphthalene to 85:15. The hydrogen solubility increased linearly with the pressure following the Henry s law for all systems. The experimental solubility data were correlated or predicted with the Peng Robinson equation of