Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Osmotic and activity coefficients of glycine, dl-a-alanine and dl-a-aminobutyric acid in aqueous solutions at temperatures between 288.15 and 303.15 K

Romero, C. M.[Carmen M.], Gonzalez, M. E.[Maria E.]
Fluid Phase Equilib. 2006, 250, 1-2, 99-104
ABSTRACT
The osmotic coefficients of glycine, dl-a-alanine and dl-a-aminobutyric acid in water were measured at 288.15, 293.15, 298.15 and 303.15 K using the isopiestic method. The activity coefficients were calculated for the amino acids and the pairwise free energy for solute solute interactions were adjusted according to the McMillan Mayer theory. The osmotic and activity coefficients of amino acids are compared with literature data when they are available and the results are discussed in terms of solute solute interactions.
Compounds
# Formula Name
1 C2H5NO2 2-aminoacetic acid
2 C4H9NO2 (.+-.)-.alpha.-aminobutyric acid
3 C3H7NO2 DL-2-aminopropanoic acid
4 H2O water
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • 4
  • Osmotic coefficient ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 1; Liquid
  • Liquid
  • Gas
  • ISOPIE
  • 48
  • POMD
  • 2
  • 4
  • Osmotic coefficient ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 2; Liquid
  • Liquid
  • Gas
  • ISOPIE
  • 48
  • POMD
  • 3
  • 4
  • Osmotic coefficient ; Liquid
  • Temperature, K; Liquid
  • Molality, mol/kg - 3; Liquid
  • Liquid
  • Gas
  • ISOPIE
  • 48