ABSTRACT

Bubble point temperatures at 95.5 kPa, over the entire composition range are measured for the binary mixtures formed byN,N-dimethyl formamide with 1,2-dichloroethane, 1,1,2,2-tetrachloroethane, trichloroethylene, tetrachloroethylene, ethanol, and iso-, sec-, and tert-butanols, by means of a Swietoslawski type ebulliometer. The measurements are fitted to the Wilson model and computed values of vapor liquid equilibria and excess Gibbs energies are tabulated and discussed.

Compounds

#	Formula	Name
1	C3H7NO	dimethylformamide
2	C2H4Cl2	1,2-dichloroethane
3	C2H2Cl4	1,1,2,2-tetrachloroethane
4	C2HCl3	trichloroethene
5	C2Cl4	tetrachloroethene
6	C2H6O	ethanol
7	C4H10O	2-methyl-1-propanol
8	C4H10O	butan-2-ol
9	C4H10O	2-methylpropan-2-ol

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	PYCNOM:UFactor:8	1
POMD	1	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	EBULLIO:UFactor:8	1
POMD	2	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	PYCNOM:UFactor:8	1
POMD	2	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	EBULLIO:UFactor:8	1
POMD	3	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	PYCNOM:UFactor:8	1
POMD	3	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	EBULLIO:UFactor:8	1
POMD	4	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	PYCNOM:UFactor:8	1
POMD	4	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	EBULLIO:UFactor:8	1
POMD	5	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	PYCNOM:UFactor:8	1
POMD	5	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	EBULLIO:UFactor:8	1
POMD	6	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	PYCNOM:UFactor:8	1
POMD	6	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	EBULLIO:UFactor:8	1
POMD	7	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	7	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	PYCNOM:UFactor:8	1
POMD	7	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	EBULLIO:UFactor:12	1
POMD	8	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	8	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	PYCNOM:UFactor:8	1
POMD	8	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	EBULLIO:UFactor:8	1
POMD	9	Refractive index (Na D-line) ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Standard Abbe refractometry	1
POMD	9	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	PYCNOM:UFactor:8	1
POMD	9	Vapor or sublimation pressure, kPa ; Liquid	Temperature, K; Liquid		Liquid Gas	EBULLIO:UFactor:8	1
POMD	1 2	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 2; Liquid	Pressure, kPa; Liquid	Liquid Gas	EBULLIO:UFactor:8	21
POMD	1 3	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 3; Liquid	Pressure, kPa; Liquid	Liquid Gas	EBULLIO:UFactor:8	21
POMD	1 4	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 4; Liquid	Pressure, kPa; Liquid	Liquid Gas	EBULLIO:UFactor:8	21
POMD	1 5	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 5; Liquid	Pressure, kPa; Liquid	Liquid Gas	EBULLIO:UFactor:8	21
POMD	6 1	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 6; Liquid	Pressure, kPa; Liquid	Liquid Gas	EBULLIO:UFactor:8	21
POMD	1 7	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 7; Liquid	Pressure, kPa; Liquid	Liquid Gas	EBULLIO:UFactor:12	21
POMD	1 8	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 8; Liquid	Pressure, kPa; Liquid	Liquid Gas	EBULLIO:UFactor:8	21
POMD	1 9	Boiling temperature at pressure P, K ; Liquid	Mole fraction - 9; Liquid	Pressure, kPa; Liquid	Liquid Gas	EBULLIO:UFactor:8	21

Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Excess Gibbs energies of selected binary mixtures formed by N,N-dimethyl formamide at 95.5 kPa

Prasad, T. E. V.[T. E. Vittal], Sravani, Y., Ranjita, V. S., Prasad, D. H. L.

ABSTRACT