The molar solution enthalpies of ionic liquids (IL) EMIBF4 (1-methyl-3-ethylimidazolium tetrafluoroborate), EMIC (1-methyl-3-ethylimidazolium chloride) and ionic solid NaBF4 at various molalities were determined by the solution-reaction isoperibol calorimeter in water at 298.15 K. In terms of a Debye-Huckel limiting term, the molar solution enthalpies of EMIBF4, EMIC and NaBF4 at infinite dilution, deltasHm , were obtained. Then the values of apparent relative molar enthalpy were calculated. Hydration heat of both cation EMI+ and anion BF4- was discussed. In terms of values of deltasHm, the reaction heat of NaBF4 + EMIC to EMIBF4 + NaCl was estimated.
Compounds
#
Formula
Name
1
Cl3Ga
gallium chloride
2
C6H11ClN2
1-ethyl-3-methylimidazolium chloride
Datasets
The table above is generated from the ThermoML associated json file (link above).
POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied;
the numbers refer to the table of compounds on the left.