Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

High-pressure viscosity behavior of x 1,1,1,2-tetrafluoroethane (HFC-134a) + (1-x) triethylene glycol dimethylether (TriEGDME) mixtures: Measurements and modeling

Monsalvo, M. A.[Matias A.], Baylaucq, A.[Antoine], Quinones-Cisneros, S. E.[Sergio E.], Boned, C.[Christian]
Fluid Phase Equilib. 2006, 247, 1-2, 70-79
ABSTRACT
In this work new dynamic viscosity measurements for binary mixtures containing a refrigerant (HFC-134a, CF3CH2F) and a lubricant (TriEGDME, CH3O(CH2OCH2)3CH3) are reported. The measurements were carried out at temperatures between 293.15 and 373.15K and pressures from 10 to 100MPa, for two mole fractions xHFC = 0.3427 and 0.5940 (a total of 100 experimental values). Since lubricants and refrigerants are in two different thermodynamic states at atmospheric pressure and ambient temperature, an especially designed falling-body viscometer has been used to perform the measurements. The data obtained for this binary system have been used to test the ability of several viscosity models having different origins and theoretical backgrounds. The considered models range from simple mixing rules, through empirical correlations, such as the self-referencing model and the LBC model, to recent approaches with a physical and theoretical background, such as the hard-sphere scheme, the free-volume model, and the friction theory.
Compounds
# Formula Name
1 C2H2F4 1,1,1,2-tetrafluoroethane
2 C8H18O4 2,5,8,11-tetraoxadodecane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 2
  • Viscosity, Pa*s ; Liquid
  • Temperature, K; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Falling or rolling sphere viscometry
  • 24
  • POMD
  • 2
  • 1
  • Viscosity, Pa*s ; Liquid
  • Pressure, kPa; Liquid
  • Temperature, K; Liquid
  • Mole fraction - 1; Liquid
  • Liquid
  • Falling or rolling sphere viscometry
  • 100