ABSTRACT

New excess volume data for four ternary mixtures were measured at 303.15 K. The mixtures included 1,3-dichlorobenzene and methyl ethyl ketone as common components. 1-propanol, 1-butanol, 1-pentanol and 1-hexanol were served as non-common components. The measured ternary excess volume (VE 123) data are negative as a function of composition in all the mixtures. Further, the experimental data were compared with those predicted by empirical equations and were analysed in terms of intermolecular interactions between component liquids.

Compounds

#	Formula	Name
1	C6H4Cl2	1,3-dichlorobenzene
2	C4H8O	butanone
3	C3H8O	propan-1-ol
4	C4H10O	butan-1-ol
5	C5H12O	pentan-1-ol
6	C6H14O	hexan-1-ol

Datasets

The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type	Compound-#	Property	Variable	Constraint	Phase	Method	#Points
POMD	1	Normal boiling temperature, K ; Liquid			Liquid Gas	Distillation	1
POMD	1	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	2	Normal boiling temperature, K ; Liquid			Liquid Gas	Distillation	1
POMD	2	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	3	Normal boiling temperature, K ; Liquid			Liquid Gas	Distillation	1
POMD	3	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	4	Normal boiling temperature, K ; Liquid			Liquid Gas	Distillation	1
POMD	4	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	5	Normal boiling temperature, K ; Liquid			Liquid Gas	Distillation	1
POMD	5	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	6	Normal boiling temperature, K ; Liquid			Liquid Gas	Distillation	1
POMD	6	Mass density, kg/m3 ; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid		Liquid	Pycnometric method	1
POMD	2 1	Excess molar volume, m3/mol ; Liquid	Mole fraction - 1; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Direct dilatometry	10
POMD	3 2 1	Excess molar volume, m3/mol ; Liquid	Mole fraction - 1; Liquid Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Direct dilatometry	10
POMD	4 2 1	Excess molar volume, m3/mol ; Liquid	Mole fraction - 1; Liquid Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Direct dilatometry	10
POMD	5 2 1	Excess molar volume, m3/mol ; Liquid	Mole fraction - 1; Liquid Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Direct dilatometry	10
POMD	2 6 1	Excess molar volume, m3/mol ; Liquid	Mole fraction - 1; Liquid Mole fraction - 2; Liquid	Temperature, K; Liquid Pressure, kPa; Liquid	Liquid	Direct dilatometry	10

Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Excess molar volumes of ternary mixtures of 1,3-dichlorobenzene and methyl ethyl ketone with 1-alkanols at 303.15K

Rajasekar, J.[Jalari], Sivakumar, K.

ABSTRACT