Thermodynamics Research Center / ThermoML | Fluid Phase Equilibria

Isobaric vapor liquid equilibria for binary systems of butyl chlorides with heptane, toluene and cyclohexane at 101.3, 80.0 and 53.3 kPa

Hidouche, M.[Malika], Dahmani, O.[Omar]
Fluid Phase Equilib. 2006, 243, 1-2, 1-8
ABSTRACT
Isobaric vapor liquid equilibrium (VLE) data are reported at 101.3, 80.0 and 53.3 kPa for six binary systems of 1-chlorobutane with heptane, cyclohexane and toluene, and 2-chlorobutane with the same hydrocarbons. The experimental isobaric T, x and y data were fitted to four twoparameter models namely Redlich Kister, NRTL (a12 = 1), Wilson and UNIQUAC. The maximum likelihood principle was applied to adjust the model parameters.
Compounds
# Formula Name
1 C4H9Cl 1-chlorobutane
2 C4H9Cl 2-chlorobutane
3 C7H8 toluene
4 C6H12 cyclohexane
5 C7H16 heptane
Datasets
The table above is generated from the ThermoML associated json file (link above). POMD and RXND refer to PureOrMixture and Reaction Datasets. The compound numbers are included in properties, variables, and phases, if specificied; the numbers refer to the table of compounds on the left.
Type Compound-# Property Variable Constraint Phase Method #Points
  • POMD
  • 1
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:24
  • 16
  • POMD
  • 2
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:24
  • 15
  • POMD
  • 3
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:48
  • 17
  • POMD
  • 4
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:24
  • 12
  • POMD
  • 5
  • Vapor or sublimation pressure, kPa ; Liquid
  • Temperature, K; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:24
  • 18
  • POMD
  • 1
  • 5
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:4
  • 58
  • POMD
  • 1
  • 5
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Gas
  • Gas
  • Liquid
  • Index of refraction calibration data
  • 58
  • POMD
  • 1
  • 4
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:4
  • 51
  • POMD
  • 1
  • 4
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Gas
  • Gas
  • Liquid
  • Index of refraction calibration data
  • 51
  • POMD
  • 1
  • 3
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:4
  • 61
  • POMD
  • 1
  • 3
  • Mole fraction - 1 ; Gas
  • Mole fraction - 1; Liquid
  • Pressure, kPa; Gas
  • Gas
  • Liquid
  • Index of refraction calibration data
  • 61
  • POMD
  • 2
  • 5
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:4
  • 59
  • POMD
  • 2
  • 5
  • Mole fraction - 2 ; Gas
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Gas
  • Gas
  • Liquid
  • Index of refraction calibration data
  • 59
  • POMD
  • 2
  • 4
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:4
  • 57
  • POMD
  • 2
  • 4
  • Mole fraction - 2 ; Gas
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Gas
  • Gas
  • Liquid
  • Index of refraction calibration data
  • 57
  • POMD
  • 2
  • 3
  • Boiling temperature at pressure P, K ; Liquid
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Liquid
  • Liquid
  • Gas
  • EBULLIO:UFactor:4
  • 60
  • POMD
  • 2
  • 3
  • Mole fraction - 2 ; Gas
  • Mole fraction - 2; Liquid
  • Pressure, kPa; Gas
  • Gas
  • Liquid
  • Index of refraction calibration data
  • 60